By John A. Schlueter (auth.), Marc Fourmigué, Lahcène Ouahab (eds.)
For a number of years, the 2 parallel worlds of Molecular Conductors in a single hand and Molecular Magnetism within the different have grown part through facet, the previous basically in keeping with radical natural molecules, the latter basically in response to the excessive spin homes of steel complexes. over the past few years although, organometallic derivatives have began to play an more and more vital function in either worlds, and feature in lots of methods contributed to open a number of passages among those worlds. This quantity acknowledges this significant rising evolution of either examine components. it isn't meant to offer a accomplished view of all attainable organometallic fabrics, and polymers for instance weren't thought of the following. relatively we current a range of the newest learn subject matters the place organometallic derivatives have been proven to play a vital position within the surroundings of undertaking and/or magnetic houses in crystalline fabrics. First, the position of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted via Schlueter, whereas Kubo and Kato describe very fresh ortho-metalated chelating ligands appended to the TTF middle and their carrying out salts. the combo of engaging in and magnetic houses and the quest for p–d interactions are analyzed in comp- mentary contributions by means of Myazaki and Ouahab, whereas Valade makes a speciality of the one classification of steel bis(dithiolene) complexes to provide upward push to superconductive molecular fabrics, in organization with natural in addition to organometallic cations.
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Extra info for Conducting and Magnetic Organometallic Molecular Materials
However, crystal structures of these salts were not reported, and details of their electrical properties and electronic states were not discussed based on their crystal structures. 2 Crystal Structure of the Cation Radical Salt [(bpy)Pt(C8H4S8)][BF4] Crystal structure data are indispensable for the discussion of the conduction mechanism in the cation radical salts based on the unsymmetrical complexes. In 2002, 42 K. Kubo and R. t. 1 Â 102 Ref.                the first crystal structure analysis of a 1:1 cation radical salt based on the unsymmetrical diimine-dithiolene Pt complex [(bpy)Pt(C8H4S8)][BF4] was reported by Kubo et al.
3 Unsymmetrical Components Based on Organometallic–Dithiolene Complexes . . . . . 1 General Features of Unsymmetrical Components Based on Organometallic Metal–Dithiolene Complexes . . . . . . . . . . . . . . . . . . . . 2 Cation Radical Salts of the Organometallic Au(III) Dithiolene Complexes . . . . . 3 Conclusion . . . . . . . . . . . . . . . . . .
Jayaswal MN, Peindy HN, Guyon F, Knorr M, Ararvari N, Fourmigue M (2004) Eur J Inorg Chem:2646 106. Fourmigue M, Huan Y-S (1993) Organometallics 12:797 107. Akamatu H, Inokuchi H, Matsunaga Y (1954) Nature 173:168 Top Organomet Chem (2009) 27: 35–53 New Molecular Architecture for Electrically Conducting Materials Based on Unsymmetrical Organometallic-Dithiolene Complexes Kazuya Kubo and Reizo Kato Abstract New molecular architecture for highly conducting molecular materials was developed with use of unsymmetrical organometallic-dithiolene complexes.
Conducting and Magnetic Organometallic Molecular Materials by John A. Schlueter (auth.), Marc Fourmigué, Lahcène Ouahab (eds.)